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Constraint driven modulation of N,N-diarylamine(s) under space limitations imprinted in 7.6.6 defect
Autorzy
Rok wydania
2026
Czasopismo
Numer woluminu
62
Strony
2976-2980
DOI
10.1039/d5cc06526g
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The behaviour within any constraint-based chemical system is strictly correlated with the potential strain-release that drives possible transformation(s) leading to the properties modification. An involvement of N,N-diarylamine into a sterically crowded system incorporating three dynamic and potentially removable hydrogens defines an unprecedented and spontaneous transformation that follows a step-by-step oxidation process via a neutral radical to form a fully conjugated diatropic system.
Adres publiczny
http://dx.doi.org/10.1039/d5cc06526g