Repozytorium

Chemoselective alcoholysis of lactide mediated by a magnesium catalyst: an efficient route to alkyl lactyllactate.

Autorzy

Agnieszka Grala

Jolanta Ejfler

Lucjan B. Jerzykiewicz

Piotr Sobota

Rok wydania

2011

Czasopismo

Dalton Transactions

Numer woluminu

40

Strony

4042-4044

DOI

10.1039/c1dt10087d

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Alkyl-(S,S)-O-lactyllactate was prepared by chemoselective alcoholysis of lactide LA mediated by a magnesium catalyst. When ROH reacted with LA it yielded the ring-opened product R-(S,S)-O-lactyllactate exclusively, which remained intact as long as LA was present in the reaction mixture. Consumption of LA caused the reaction to proceed further giving R-(S)-lactate.

Adres publiczny

http://dx.doi.org/10.1039/c1dt10087d

Strona internetowa wydawcy

https://www.rsc.org/