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One-pot synthesis of a new magnetically coupled heterometallic Cu2Mn2[2 x 2] molecular grid.
Autorzy
Rok wydania
2010
Czasopismo
Numer woluminu
49
Strony
4750-4752
DOI
10.1021/ic100555s
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The heterometallic [2 × 2] grid-type complex [Cu2Mn2(pop)4(OAc)4]·7H2O (1) has been selectively synthesized in a targeted one-pot reaction. Single-crystal X-ray analysis shows the expected structure with identical metal ions located at diagonal vertices of the grid. Magnetochemical studies reveal that 1 has a ferrimagnetic spin ground state with some admixture of low-lying excited states.
Adres publiczny
https://doi.org/10.1021/ic100555s
Strona internetowa wydawcy
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