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Inne
Products of the reaction of 9-nickelafluorenyllithium with iodine and different cyclopentadienyl-metal complexes.
Autorzy
Rok wydania
2009
Czasopismo
Numer woluminu
362
Strony
3338-3342
DOI
10.1016/j.ica.2009.03.013
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
9-Nickelafluorenyllithium (1) reacted with iodine and then with various CpxM complexes (Cpx = Cp, Cp∗, M = Na, Mg, Li) in different solvents. The products (π-allyl complexes), isolated from these reactions, were formed via addition of the biphenyl ligand to the Cp ring originally bonded to the Ni atom. Stereospecifity of the reactions depended on the used solvent. π-Allyl compounds 2, 3 and 4 were characterized by X-ray single crystal analysis.
Słowa kluczowe
Nickel, Addition, π-Allyl complexes, Metallacyclic compounds
Adres publiczny
https://doi.org/https://doi.org/10.1016/j.ica.2009.03.013
Strona internetowa wydawcy
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