Repozytorium

A new complex of europium(II) with edta - structure and spectroscopy.

Autorzy

Rafał Janicki

Anna Mondry

Przemysław Starynowicz

Rok wydania

2005

Czasopismo

Zeitschrift für Anorganische und Allgemeine Chemie

Numer woluminu

631

Strony

2475-2477

DOI

10.1002/zaac.200500236

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

A new complex of europium(II) with ethylenediaminetetraacetic acid was obtained by electrochemical reduction. The compound is composed of polymeric chains, guanidinium cations and water molecules. The Eu2+ cation is eight-coordinate (two nitrogen atoms and six carboxylate oxygen atoms), and contrary to europium(III) complexes with edta, does not contain water molecules in the first coordination sphere. Relationships between the coordination mode and IR as well as UV–Vis spectra are discussed.

Adres publiczny

https://doi.org/10.1002/zaac.200500236

Strona internetowa wydawcy

onlinelibrary.wiley.com

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