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Inne
3D supramolecular network constructed by intermolecular interactions in mixed ligand complex of zinc.
Autorzy
Rok wydania
2005
Czasopismo
Inorganic Chemistry Communications
Numer woluminu
8
Strony
1090-1093
DOI
10.1016/j.inoche.2005.09.009
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
New complex [Zn(quin-2-c) 2 (Him) 2 ] (quin-2-c=quinoline-2-carboxylate ion, Him=imidazole) was synthesized by self assembly and its structure was determined by X-ray analysis. The compound crystallizes in P21/c space group. Four independent molecules of complex are present in the structure. Strong hydrogen bonds create three different 1D chains which are collected in two different layers. The alternately packed layers form the 3D supramolecular structure. The interchain and interlayer contacts are of the C–H⋯O, π⋯π and C–H⋯π type. The influence of strong hydrogen bond on the vibrational characteristics of the monodentately coordinated carboxylate group in zinc complexes with quin-2-c ion is discussed.
Słowa kluczowe
Zinc complex, Crystal structure, Supramolecular network, Hydrogen bonds, Infrared spectra
Adres publiczny
http://dx.doi.org/ 10.1016/j.inoche.2005.09.009
Strona internetowa wydawcy
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