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Raman spectroscopy of formic acid and its dimers isolated in low temperature argon matrices.
Autorzy
Rok wydania
2009
Czasopismo
Numer woluminu
468
Strony
176-183
DOI
10.1016/j.cplett.2008.12.011
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Raman spectroscopy combined with matrix isolation technique was employed to study formic acid monomer and its dimers. Nine fundamentals of the HCOOH monomer were identified. Additionally, the OH torsion overtone is observed and it is engaged in Fermi resonance with the δCOH mode. Several bands of the cyclic (C2h) dimer were identified and assigned. The less stable open form (Cs) of the dimer was also present in the experiment. Three intermolecular modes for the cyclic and one mode for the open dimer were found in the low frequency region. The experimental studies were supported by harmonic and anharmonic DFT calculations.
Adres publiczny
https://doi.org/10.1016/j.cplett.2008.12.011
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