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trans-Iodo(p-iodophenyl)bis(triphenylphosphine)palladium(II).
Autorzy
Rok wydania
2006
Czasopismo
Acta Crystallographica Section E: Structure Reports Online
Numer woluminu
E62
Strony
m1428-m1430
DOI
10.1107/S1600536806018903/cf2020Isup2.hkl
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The title compound, trans-[Pd(C6H4I)I(C 18H15P)2], has been crystallized from dichloromethane. The crystal structure of this complex reveals a slightly distorted square-planar coordination geometry of the Pd atom, which lies on a twofold rotation axis. The P atoms in the triphenylphosphine ligands lie slightly out of the planes of the phenyl rings. The crystal structure is stabilized by short intermolecular I⋯I contacts, weak C - H⋯π(arene) hydrogen bonds and π-π stacking interactions. © 2006 International Union of Crystallography. All rights reserved.
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