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Kolekcje
Inne
Synthesis, spectroscopic characterization, X-ray structure and magnetic properties of [Cu(hmquin-7-COOH)2(MeOH)] complex.
Autorzy
Rok wydania
2009
Czasopismo
Numer woluminu
28
Strony
3774-3780
DOI
10.1016/j.poly.2009.07.057
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The reaction of copper(II) chloride dihydrate and 8-hydroxy-2-methylquinoline-7-carboxylic acid (Hhmquin-7-COOH) leads to [Cu(hmquin-7-COOH)2(MeOH)]. The compound has been studied by IR, UV–Vis, EPR spectroscopy and X-ray crystallography. X-ray studies confirm bidentate coordination mode of the hmquin-7-COOH anions via the pyridine nitrogen atom and deprotonated hydroxyl group. The COOH groups of the hmquin-7-COOH ligands are potentially available for further conjugation. The title complex has been additionally studied by magnetic measurement. The TDDFT/PCM calculations have been employed to discuss the electronic spectrum of [Cu(hmquin-7-COOH)2(MeOH)] in more detail.
Słowa kluczowe
Copper(II), 8-Hydroxy-2-methylquinoline-7-carboxylic acid, X-ray structure, Magnetic properties and TDDFT calculations
Adres publiczny
https://doi.org/10.1016/j.poly.2009.07.057
Strona internetowa wydawcy
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