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Reaction of antiaromatic porphyrinoid with active methylene compounds
Autorzy
Rok wydania
2019
Czasopismo
Numer woluminu
6
Strony
2924-2933
DOI
10.1039/c9qo00679f
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Active methylene compounds which have two electron-withdrawing groups, such as ethyl 2-cyanoacetate, 3-oxobutanenitrile, cyclohexane-1,3-dione, malononitrile, pentane-2,4-dione, and ethyl acetoacetate, react regioselectively with antiaromatic norcorrolatonickel(II) in THF at room temperature in the presence of Cs2CO3 yielding new types of norcorrole derivatives retaining the spectral, magnetic, and redox properties of the starting macrocycle.
Adres publiczny
http://dx.doi.org/10.1039/c9qo00679f
Strona internetowa wydawcy
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