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Homo- and heteroleptic zinc aminophenolates as initiators for lactide polymerization.
Autorzy
Rok wydania
2008
Czasopismo
Strony
6556-6562
DOI
10.1039/B808882A
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The reaction of ZnEt2 with one or two equivalents of aminophenolate ligand N-[methyl(2-hydroxy-3,5-di-tert-butylphenyl)]-N-methyl-N-cyclohexylamine gives hetero- and homoleptic molecular compounds [(μ,η2-L2)ZnEt]2 and [Zn(η2-L2)2]. The later is most probably a mixture of diastereoisomers that in solution shows an interesting dynamic behaviour. Both complexes as well as the BnOH derivative of the latter, [(η2-L2)Zn(μ-BnO)]2, proved excellent initiators for lactide polymerization.
Adres publiczny
DOI https://doi.org/10.1039/B808882A
Strona internetowa wydawcy
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