Repozytorium

Synthesis, structure, and magnetic properties of a mononuclear chiral (acetato)bis(aminoalkoxido)manganese(III) complex.

Autorzy

Arkadiusz Kornowicz

Michał Terlecki

Daniel Prochowicz

Céline Pichon

Iwona Justyniak

Wojciech Bury

Zbigniew Wróbel

Jean-Pascal Sutter

Janusz Lewiński

Rok wydania

2017

Czasopismo

European Journal of Inorganic Chemistry

Strony

1392-1395

DOI

10.1002/ejic.201700084

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

A new synthetic procedure was developed to obtain a novel mononuclear chiral square‐pyramidal (acetato)bis(aminoalkoxido)MnIII complex from a heterometallic ZnII/MnII system with a crucial role for O2 in the process. The resulting compound was characterized spectroscopically and crystallographically, and its magnetic properties were determined. The MnIII ion exhibits magnetic anisotropy with a zero‐field splitting D parameter equal to –2.95 cm–1

Słowa kluczowe

Aminoalkoxides, magnetic properties, manganese, Supramolecular chemistry, synthetic methods

Adres publiczny

http://dx.doi.org/10.1002/ejic.201700084

Strona internetowa wydawcy

onlinelibrary.wiley.com

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