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Inne
Hex-1-ene hydroformylation catalyzed by Rh(acac){P(OPh)3}3 modified with amines, formation of reactive HRh(CO){P(OPh)3}3 and unreactive Rh4(CO)8{P(OPh)3}4 species.
Autorzy
Rok wydania
1990
Czasopismo
Journal of Organometallic Chemistry
Numer woluminu
390
Strony
105-111
DOI
10.1016/0022-328X(90)85086-E
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Pyridines and amines have been used as modifying ligands in the hex-1-ene hydroformylation reaction catalyzed by Rh(acac){P(OPh)3}2. Aldehydes (n + iso) were obtained in 80–85% yield. The active form of the catalyst has been isolated as the solid HRh(CO){P(OPh)3}3. Another complex formed in the reaction of Rh(acac){P(OPh)3}2 with H2 and CO in the presence of pyridine, Rh4(CO)8{P(OPh)3}4, is catalytically inactive.
Adres publiczny
https://doi.org/10.1016/0022-328X(90)85086-E
Strona internetowa wydawcy
Podobne publikacje
1994
1,5-hexadiene selective hydroformylation reaction catalyzed with Rh(acac){P(OPh)3}2/P(OPh)3 and Rh(acac)(CO)(PPh3)/PPh3 complexes.
Trzeciak Anna M., Ziółkowski Józef J.
1991
Effect of modifying ligands (P(OPh)3, PPh3, dppe and cp2Zr(CH2PPh2)2) on hex-1-ene hydroformylation catalyzed by [HRh{P(OPh)3}4] and [HRh(CO) {P(OPh)3}3].
Trzeciak Anna M., Ziółkowski Józef J., Choukroun R.
1991
Influence of the modification of the ligands on hex-1-ene hydroformylation catalyzed by [HRh{P(OPh)3}4] and [HRh(CO){P(OPh)3}3]. Catalytic activity of the system [HRh{P(OPh)3}4] + Cp2Zr(CH2PPh2)2.
Trzeciak Anna M., Ziółkowski Józef J., Choukroun R.