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Synthesis, structure and catalytic activity of an oxorhenium(V) complex containing chelating phosphite ligand.
Autorzy
Rok wydania
1992
Czasopismo
Journal of Coordination Chemistry
Numer woluminu
26
Strony
79-82
DOI
10.1080/00958979209407915
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The new violet oxorhenium(V) complex ReOCl3(pinacop) {pinacop = (OCMe2CMe2O)POCMe2CMe2OP (OCMe2CMe2O)} was obtained by reaction of ReOCl3(OPPh3)(SMe2) with a stoichiometric amount of pinacop. Facial geometry was determined by spectroscopic means and preliminary results from an X-ray crystallographic study. The catalytic properties of the title compound in oxygen atom transfer reactions are discussed.
Słowa kluczowe
oxorhenium(V), chelating phosphite, oxygen atom transfer, X-ray structure
Adres publiczny
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