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Inne
Cation-templated 2-D Mn(II)-oxalate framework with an acyclic tetrameric water cluster.
Autorzy
Rok wydania
2011
Czasopismo
Journal of Coordination Chemistry
Numer woluminu
64
Strony
2367-2376
DOI
10.1080/00958972.2011.586031
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The single-crystal X-ray structure of a cation-templated manganese–oxalate coordination polymer [NH(C2H5)3][Mn2(ox)3] · (5H2O)] (1) is reported. In 1, triethylammonium cation is entrapped between the cavities of 2-D honeycomb layers constructed by oxalate and water. The acyclic tetrameric water clusters and discrete water assemble the parallel 2-D honeycomb oxalate layers via an intricate array of hydrogen bonds into an overall 3-D network. The magnetic susceptibility, with and without the water cluster, are reported with infrared and EPR studies.
Słowa kluczowe
Mn–oxalate framework, Encapsulated triethylammonium cation, Tetrameric water cluster
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