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Monodentate coordinated chromate(VI) ion in [Cu(phen)2OCrO3](phen)0.5·4H2O completing the square pyramidal geometry of the copper(II) in the solid state.
Autorzy
Rok wydania
2010
Czasopismo
Numer woluminu
21
Strony
337-345
DOI
10.1007/s11224-009-9539-4
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Novel copper(II) complex of the formula [Cu(phen)2OCrO3](phen)0.5 ·4H2O (1) (phen = 1,10-phenantroline) was prepared in the crystalline form and characterized by X-ray diffraction and spectroscopic methods (IR-FIR, NIR-Vis–UV, EPR). In the solid state, the CuN4O chromophore adopts a slightly distorted square-pyramidal geometry around the Cu2+ ion with a magnitude of a distortion parameter τ = 0.14. The chromate unit in (1) was found to be a monodentate.
Słowa kluczowe
atom, 10-phenantroline, Chromate anion, Cooper(II) complex, X-ray diffraction, NIR-Vis–UV spectroscopy, Gaussian analysis
Adres publiczny
http://dx.doi.org/10.1007/s11224-009-9539-4
Strona internetowa wydawcy
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