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Synthesis and structural characterization of the novel unusual oxido-bridged rhenium complex with Re atoms in two different coordination environments.
Autorzy
Rok wydania
2010
Czasopismo
Inorganic Chemistry Communications
Numer woluminu
13
Strony
782-785
DOI
10.1016/j.inoche.2010.03.046
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A new binuclear mixed-valence complex [ReCl4(py)(μ-O)Re(py)4Cl]·2py was obtained by solvothermal synthesis in a Berghoff autoclave. It has been studied by IR, reflectance spectra, TGA and X-ray measurements, which support the assumption, that two Re centres with different coordination environments are present. Most plausible, yet not unambiguous oxidation state assignment is ReIII/IV.
Słowa kluczowe
crystal structure, Rhenium mixed-valence complex, Solvothermal synthesis
Adres publiczny
https://doi.org/10.1016/j.inoche.2010.03.046
Strona internetowa wydawcy
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