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Light-induced, site-selective isomerization of glyoxylic acid in solid xenon.
Autorzy
Rok wydania
2014
Czasopismo
Numer woluminu
616-617
Strony
91-97
DOI
10.1016/j.cplett.2014.10.023
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The isomerization of glyoxylic acid (GA) and its water complex was studied in a low temperature xenon matrix. The aim of these studies was to understand how xenon environment affects the cis-trans GA interconversion upon near infrared irradiation. In solid xenon, the GA conformers are embedded in two different matrix sites. These show up as different vibrational bands of GA that exhibit different kinetic rates of isomerization. Upon complexation with water, the isomerization process slows down. Xenon matrix appears not to affect energy relaxation process via intramolecular or intermolecular hydrogen bond as compared with previous experiments in an argon.
Adres publiczny
http://dx.doi.org/10.1016/j.cplett.2014.10.023
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