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Inne
The hydrogen bond in 2-(N,N-dimethylamino-N-oxymethyl)-4,6-dimethylophenol.
Autorzy
Rok wydania
1989
Czasopismo
Journal of Molecular Structure
Numer woluminu
195
Strony
33-41
DOI
10.1016/0022-2860(89)80156-5
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The X-ray diffraction studies have been carried out on the monohydrate of 2-(N,N-dimethylamino-N-oxymethyl)-4,6-dimethylophenol (I). The crystals are monoclinic, space group P21/c, with a = 21.921(6) Å, b = 5.058(2) Å, c = 11.748(3) Å; β = 113.66(4)°, V = 1193.1(4) Å3, Z = 4. The length of the intramolecular OH⋯O hydrogen bond is 2.541(6) Å. The crystallographic data and the UV and IR absorption spectra indicate that this bond is considerably weaker than that reported previously for 2-(N,N-diethylamino-N-oxymethyl)-4,6-dichlorophenol (II), where a quasisymmetric bridge was found.
Adres publiczny
https://doi.org/10.1016/0022-2860(89)80156-5
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